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Beilstein J. Org. Chem. 2017, 13, 1498–1506, doi:10.3762/bjoc.13.148
Graphical Abstract
Figure 1: Phenylacetylene polymerization of FhuA ΔCVFtev [29] refolded in a polymer or small amphiphilic molecule...
Figure 2: Hydrophobic transmembrane region of FhuA ΔCVFtev [29] stabilized by ≈200 MPD molecules. MPD is illustra...
Scheme 1: Coupling of [Rh]-1 to the open channel protein FhuA ΔCVFtev. SDS, sodium dodecyl sulfate; THF, tetr...
Figure 3: Circular dichroism spectra of 2 refolded in 2-methyl-2,4-pentanediol (MPD, red) and polyethylene–po...
Figure 4: MALDI–TOF mass spectra of apo FhuA ΔCVFtev (red; calculated m/z = 5902.6; found: m/z = 5911.7) and 2...
Beilstein J. Org. Chem. 2016, 12, 1314–1321, doi:10.3762/bjoc.12.124
Scheme 1: Syntheses to Cu(I) complex bearing a NHC ligand.
Scheme 2: Synthesis of Cu(II) terpyridyl complexes.
Scheme 3: Anchoring and refolding of the biohybrid copper complexes.
Figure 1: CD spectra of refolded catalysts 17–19 (red: 17, black: 18, blue: 19).
Figure 2: Temperature-dependent CD spectra of catalyst 17.
Figure 3: MALDI–TOF mass spectra (black: 17, red: FhuAΔCVFtev).